[Cl....CH3....Cl]- Central Barrier Dyanamics
Sample trajectories from a 300 K Boltzmann Distribution Transition State theory and RRKM theory predict negligible central barrier recrossing. The average RRKM lifetime of the ion-dipole complex is 4 ps. The trajectories are integrated for 3 ps. No products are formed, while RRKM theory predicts 50% of the trajectories should form products.